Non-acoustical and acoustical properties of reticulated and partially reticulated polyurethane foams

A series of measurements on four polyurethane foam samples with pore membranes and a polyurethane foam sample without pore membranes have been made. Tortuosity has been deduced using the ultrasonic slope method. It has been found that the deduced value of tortuosity depends on the measurement temperature and for two of the polyurethane foam samples with many pore membranes physically meaningful values of tortuosity cannot be obtained at a temperature of around 25 °C. However more realistic values of tortuosity have been obtained by from measurements at or around the glass transition temperature of polyurethane foam (i.e. at ?20 °C) when using the ultrasonic slope method.Flow resistivity, Young’s moduli and loss factors have been measured also.Vibration of the pore membranes has been observed to influence the effective density and characteristic impedance derived from the surface impedance measured in an impedance tube. This paper discusses relationships between membrane vibration and the slow and fast compressional waves. The relative merits of predictions based on rigid-porous models and the Biot–Johnson–Champoux–Allard model are discussed also.     

Calculation of the stabilization energies of oxidatively damaged guanine base pairs with guanine

DNA is constantly exposed to endogenous and exogenous oxidative stresses. Damaged DNA can cause mutations, which may increase the risk of developing cancer and other diseases. G:C-C:G transversions are caused by various oxidative stresses. 2,2,4-Triamino-5(2H)-oxazolone (Oz), guanidinohydantoin (Gh)/iminoallantoin (Ia) and spiro-imino-dihydantoin (Sp) are known products of oxidative guanine damage. These damaged bases can base pair with guanine and cause G:C-C:G transversions. In this study, the stabilization energies of these bases paired with guanine were calculated in vacuo and in water. The calculated stabilization energies of the Ia:G base pairs were similar to that of the native C:G base pair, and both bases pairs have three hydrogen bonds. By contrast, the calculated stabilization energies of Gh:G, which form two hydrogen bonds, were lower than the Ia:G base pairs, suggesting that the stabilization energy depends on the number of hydrogen bonds. In addition, the Sp:G base pairs were less stable than the Ia:G base pairs. Furthermore, calculations showed that the Oz:G base pairs were less stable than the Ia:G, Gh:G and Sp:G base pairs, even though experimental results showed that incorporation of guanine opposite Oz is more efficient than that opposite Gh/Ia and Sp.     

Differential cross section and photon-beam asymmetry for the gamma n --> K+ Sigma- reaction at E gamma = 1.5-2.4 GeV

Differential cross sections and photon-beam asymmetries have been measured for the gamma n --> K+ Sigma- and gamma p --> K+Sigma0 reactions separately using liquid deuterium and hydrogen targets with incident linearly polarized photon beams of E gamma = 1.5-2.4 GeV at 0.6 < cos ThetacmK< 1. The cross section ratio of sigma K+ Sigma-/sigma K+ Sigma0, expected to be 2 on the basis of the isospin 1/2 exchange, is found to be close to 1. For the K+ Sigma- reaction, large positive asymmetries are observed, indicating the dominance of K* exchange. The large difference between the asymmetries for the K+ Sigma- and K+ Sigma0 reactions cannot be explained by simple theoretical considerations based on Regge model calculations.     

Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide

Trifluoromethylation of aromatic and hetero-aromatic compounds by CF₃I in the presence of Fe(II) compound, H₂O₂ and dimethylsulfoxide was investigated. Various trifluoromethylated benzene derivatives, six-membered nitrogen-containing aromatic compounds and five-membered hetero-aromatic compounds were obtained under mild conditions. General orientation of electrophilic substitution of aromatic compounds was observed similarly as reported in other radical trifluoromethylation previously.     

Development and flow evaluation of electro-rheological nano-suspensions

An attempt has been made to develop a candidate for electro-rheological (ER) nano-suspensions based on anatase titanium dioxide with a particle diameter around 300 nm. The micro-gap flow behavior and microstructure were evaluated for a suspension with a particle volume fraction of 8.8 vol.%. The ER effect was investigated for the nano-suspension. The effect of shearing time on the ER responses was also investigated. The ER effect was discussed in comparison to the effect previously reported for the nano-suspension based on rutile titanium dioxide with a particle diameter around 15 nm.     

Low-temperature formation of positronium in nonpolymer organic systems

The phenomenon of the low-temperature formation of positronium (bound electron-positron system) observed during positron irradiation of a test substance is discussed. The effect is additional relative to the formation of positronium under normal conditions and, like the principal phenomenon, is radiation-chemical in nature. This effect has been discovered and studied mainly for polymers, in which the role of weakly bound electrons and positron localization (trapping) in the intensity of manifestation of this phenomenon was revealed. This review focuses on studies concerning barely investigated nonpolymer (polar and nonpolar) organic systems, in which a relatively high mobility of molecules as compared to polymers can open an opportunity for a more pictorial manifestation of positron and electron trapping by polar centers, both belonging to separate molecules and resulting from collective orientation of the molecules.     

On-wafer thermomechanical characterization of a thin film polyimide formed by vapor deposition polymerization for through-silicon via applications: Comparison to plasma-enhanced chemical vapor deposition SiO2

Thin-film polyimides were prepared by solvent-less vapor deposition polymerization (VDP) from pyromellitic dianhydride and 4,4′-oxydianiline at 200 °C for liner dielectric formation of vertical interconnects called through-silicon vias (TSVs) used in three-dimensionally stacked integrated circuit (3DICs). FTIR, synchrotron XPS, and TDS were employed for determining the imidization ratio, and in addition, the mechanical properties, coefficient of thermal expansion and Young's modulus, of the VDP polyimide were characterized on Si wafers. The VDP polyimide exhibited extremely high conformality, beyond 75%, toward high-aspect-ratio deep Si holes, compared with conventional SiO₂ prepared by plasma-enhanced chemical vapor deposition. The adhesion between the VDP polyimide and Si wafer was enhanced by an Al-chelate promotor. Remarkably, the VDP polyimide TSV liner dielectrics showed much less thermomechanical stresses applied to the Si surrounding the TSVs than the plasma-chemical vapor deposition SiO₂. The small keep-out zone is expected for scaling down highly reliable 3DICs for the upcoming real artificial intelligence society.     

Time-Dependent Coupled-Channel Calculations of the Annihilation Rate in Positron–Hydrogen Collisions

The effect of aluminum content and degree of crystallinity upon the possible values for both the polar coordinates (Θ and ?) of the magnetic hyperfine field direction with respect to the electric field gradient (EFG) frame of reference and for the asymmetry parameter (η) in synthetic Al-goethites was determined experimentally from their variable temperature Mössbauer spectra. The range of values for these parameters was examined using the ratio R of the quadrupole shift to the quadrupole splitting. It was found that R varies in the range ?0.62≤R≤?0.55, implying that, considering all the samples, ～65°≤Θ≤90°, ～?1≤cos?2?≤?0.25 and ～0.1≤η≤1. Additionally, the principal components of the EFG tensor and η were calculated using the simple point charge model.

     

Multiaxial deformations of end‐linked poly(dimethylsiloxane) networks. III. Effect of entanglement density on strain‐energy density function

Strain‐energy density functions (W) of end‐linked polydimethylsiloxane (PDMS) networks with different entanglement densities were estimated as a function of the first and second invariants I₁ and I₂ of Green's deformation tensor on the basis of the quasi‐equilibrium biaxial stress‐strain data. Entanglement densities in the PDMS networks were controlled by varying the precursor PDMS concentration (?₀) in end‐linking. The deduced functional form of W [W = C₁₀(I₁ ? 3) + C₀₁(I₂ ? 3) + C₁₁(I₁ ? 3)(I₂ ? 3) + C₂₀(I₁ ? 3)² + C₀₂(I₂ ? 3)²] is independent of the degree of dilution at network preparation. The contribution of each term in I₁ and I₂ to total energy depends on whether the precursor PDMS solution before end‐linking belongs to the concentrated regime ?₀ > ?_c where many entanglement couplings of precursor chains exist or the moderately concentrated regime ?₀ < ?_c where pronounced entanglement couplings of precursor chains are absent. These results suggest that the rubber elasticity of the end‐linked networks is significantly influenced by the entangled state of precursor chains before end‐linking, and the extra terms in the estimated W that are absent in the prediction of the classical rubber elasticity theories [W = C (I₁ ? 3)] mainly originate from the effect of trapped entanglements. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2780–2790, 2002